[CHM 115] Fwd: Re: Lab
Andrew J. Pounds
pounds_aj at mercer.edu
Sun Oct 26 19:01:33 EDT 2014
-------- Original Message --------
Subject: Re: Lab
Date: Sun, 26 Oct 2014 19:00:24 -0400
From: Andrew J. Pounds <pounds_aj at mercer.edu>
Reply-To: pounds_aj at mercer.edu
The following reaction takes place in
HCl + NaOH -> NaCl + H2O
The density of the NaCl solution is listed on the report form.
On 10/26/14 18:56, wrote:
>
> So for the mass of the solution for reaction three do I need to know
> the density of HCl? It isn't listed in the lab report form so can I
> just assume it's 1 g/mL?
>
> On Oct 26, 2014 5:44 PM, "Andrew J. Pounds" <pounds_aj at mercer.edu
> <mailto:pounds_aj at mercer.edu>> wrote:
>
> On 10/26/14 15:19, wrote:
>> Hi Dr. Pounds!
>> I'm trying to do the lab, and we either really messed up in lab
>> or I'm calculating the deltaH values for reactions three and four
>> wrong. I think my mistake might be in calculating the mass of the
>> solution for these reactions. Could you give me any pointers for
>> calculating the mass of the solution for reactions three and four?
>> Thanks!
>>
>
> So, in the equation $q = m c_s \Delta T$ you need to use the mass
> of the solution. You know the volume and the density of the
> solution is listed on the lab report form. You can therefore use
> $m = \rho V$ to compute the mass of the solutions. The specific
> heats for these solutions can also be found on the report form.
>
> Now, when it comes to $\Delta H$, you have to remember that it is
> the constant volume heat capacity on a per mole basis. So take
> your $q$ that you determined and divide it by the moles of substance.
>
> In the case of the dissolution of NaOH you have roughly 2 grams of
> NaOH. Convert this to moles (2 g / 40 g/mol) = 0.05. So your
> enthalpy of reaction for the dissolution of NaOH should be $q / 0.05$.
>
> In the case of the reaction of NaOH (aq) with HCl (aq) you have 50
> ml of 1 M NaOH (that would also be 0.05 moles), so divide the heat
> by that amount to get the enthalpy like you did before.
>
> Hopefully that give you enought to get through the rest of the
> lab, but let me know if you have any questions.
>
>
>
>
>
> --
> Andrew J. Pounds, Ph.D. (pounds_aj at mercer.edu <mailto:pounds_aj at mercer.edu>)
> Professor of Chemistry and Computer Science
> Mercer University, Macon, GA 31207(478) 301-5627 <tel:%28478%29%20301-5627>
> http://faculty.mercer.edu/pounds_aj
>
--
Andrew J. Pounds, Ph.D. (pounds_aj at mercer.edu)
Professor of Chemistry and Computer Science
Mercer University, Macon, GA 31207 (478) 301-5627
http://faculty.mercer.edu/pounds_aj
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