[CHM 181] Calibration Plot and Energies
Andrew J. Pounds
pounds_aj at mercer.edu
Tue Mar 12 17:23:08 EDT 2024
So for the lab that is due tomorrow night you need to turn in a
calibration plot using ONLY THE MERCURY (Hg) LAMP data. I am attaching
a sample plot ( do not try to turn my plot in -- you'll end up in front
of the honor council -- use your own data ).
Here is the link to the sample plot.
<http://theochem.mercer.edu/chm181/atomspec2.png>
Once you make your own plot you can use it to determine the wavelengths
of the lines from the other lights and salts. You do not have to do the
candle!
Finally, to calculate the energy for the for the mercury lines you have
to use the equation E=hcλE=\frac{h c}{\lambda}
Where h is Planck's constant in J sec, c is the speed of light in
meters/sec and lambda is the wavelength in meters. Use nanometers on
your graph but in your calculation of energy remember to convert to meters.
Example: A photon with a wavelength of 418 nm has an energy of
E = (6.626x10^-34)(3x10^8)/(418x10^-9) = 4.756x10^-19 Joules
4.756x10^-19 x 6.022x10^23 = 286400 Joules / mol = 286.4 kJ/mol
--
*Andrew J. Pounds, Ph.D.*
/Professor of Chemistry and Computer Science/
/Director of the Computational Science Program/
/Mercer University, Macon, GA, 31207 (478) 301-5627 /
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