[CHM 112] Help with Concentration Kinetics Lab
Andrew J. Pounds
pounds_aj at mercer.edu
Wed Jul 3 21:55:46 EDT 2013
For the concetration Kinetics Lab you will make TWO graphs. Using the
first set of data on the report form (the $I^-$ effect) you will plot
the natural log of the rate on the Y axis and the natural log of the
$I^-$ concentration on the X axis. Determine the slope of this line.
Then round the slope to the nearest whole number and that will be the
order with respect to $I^-$.
Remember -- the rate you are measuring is always for the PEROXIDE so it
is consistent between the first part of the lab and the second part of
the lab.
For the second part of the lab repeat what you did in the first part but
now plot where you look at the natural log of the rate on the Y axis and
the natural log of the $H_2O_2$ concentration on the X axis. Again
determine the slope and then convert this to a whole number to determine
the order with respect to peroxide.
Now -- in the last part of the lab you need to calculate the rate
constant from all of your trials. This is pretty easy, take each line
of data and "solve for k"
\documentclass{article} \usepackage[utf8x]{inputenc}
\usepackage[version=3]{mhchem} \pagestyle{empty} \begin{document}
$\mathrm{RATE}$ = k [$I^-$]$^m $[$H_2O_2$]$^n$ %this is where your LaTeX
expression goes \end{document}
Whey you have just determined the values for the reaction orders. You
should get 8 values for k that should, theoretically, be close to each
other. Average all of them and report this value.
--
Andrew J. Pounds, Ph.D. (pounds_aj at mercer.edu)
Professor of Chemistry and Computer Science
Mercer University, Macon, GA 31207 (478) 301-5627
http://faculty.mercer.edu/pounds_aj
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