[CHM 331] Re: Book problem 10.59 hw set 4

Andrew J. Pounds pounds_aj at mercer.edu
Sun Oct 9 07:08:07 EDT 2011


  On 10/08/2011 04:42 PM,  wrote:
> Dr. Pounds,
>
> I am working on 10.59 from the book for hw problem set 4.  I have 
> found the radial and angular nodes for the orbitals, but I am not sure 
> how to find the magnitude of angular momentum.  What is that referring 
> to?  I have been looking at pg. 362 in the book but I'm still not sure 
> what equation to use.  Can you point me in the right direction to 
> solve this problem?
>
> Thanks! Hope you're having a good weekend!
>
>

The magnitude is simply the value /L/ from  eqn 362 with the /l/ values 
being determined from the mapping to the orbital.

s orbital -> l=0
p orbital -> l=1
d orbital -> l=2
f orbital -> l=3

so, for example, a 3d orbital should have angular momentum magnitide of 
Sqrt[6] hbar.

One parting point -- note that this problem is asking you about the 
magnitude of the total angular momentum and not asking you anything 
about resolving the momentum into it's vector components.



-- 
Andrew J. Pounds, Ph.D.  (pounds at theochem.mercer.edu)
Associate Professor of Chemistry and Computer Science
Mercer University,  Macon, GA 31207   (478) 301-5627

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