[CHM 331] Re: Book problem 10.59 hw set 4
Andrew J. Pounds
pounds_aj at mercer.edu
Sun Oct 9 07:08:07 EDT 2011
On 10/08/2011 04:42 PM, wrote:
> Dr. Pounds,
>
> I am working on 10.59 from the book for hw problem set 4. I have
> found the radial and angular nodes for the orbitals, but I am not sure
> how to find the magnitude of angular momentum. What is that referring
> to? I have been looking at pg. 362 in the book but I'm still not sure
> what equation to use. Can you point me in the right direction to
> solve this problem?
>
> Thanks! Hope you're having a good weekend!
>
>
The magnitude is simply the value /L/ from eqn 362 with the /l/ values
being determined from the mapping to the orbital.
s orbital -> l=0
p orbital -> l=1
d orbital -> l=2
f orbital -> l=3
so, for example, a 3d orbital should have angular momentum magnitide of
Sqrt[6] hbar.
One parting point -- note that this problem is asking you about the
magnitude of the total angular momentum and not asking you anything
about resolving the momentum into it's vector components.
--
Andrew J. Pounds, Ph.D. (pounds at theochem.mercer.edu)
Associate Professor of Chemistry and Computer Science
Mercer University, Macon, GA 31207 (478) 301-5627
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